A Companion to First Ladies (Wiley Blackwell Companions to

This quantity explores greater than centuries of literature at the First girls, from Martha Washington to Michelle Obama, delivering the 1st historiographical review of those very important ladies in U.S. heritage.

• Underlines the transforming into scholarly appreciation of the 1st girls and the evolution of the location because the 18th century
• Explores the influence of those girls not just on White housework, yet on elections, presidential guidelines, social motives, and in shaping their husbands' legacies
• Brings the 1st girls into crisp historiographical concentration, assessing how those ladies and their contributions were perceived either in well known literature and scholarly debate
• presents concise biographical remedies for every First woman

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The direct reaction field (DRF) model slightly modifies the DID model to also take into account electron wavefunction overlap effects. This more accurate model was initially used to calculate the third-order Raman response for liquid Xe and it proved to be slightly more accurate than the DID model in matching the experimental signal [51]. The real test of the model came when it was applied to both the third-order [52] and the fifth-order Raman response of CS2 [53]. 24 TIME-RESOLVED SPECTROSCOPY IN COMPLEX LIQUIDS Four models were applied to the simulation: (1) the first model simply uses the molecular polarizabilities for the interaction induced effects (MOL), (2) the second approximation uses the DID model, (3) the third approximation takes into the account the extended structure of the molecules and uses the atomic polarizabilities to account for induced multipoles in the interaction (POL), and (4) the most complicated and computationally intensive model is the DRF model where electron wavefunction overlap is added to the many-body effects.

In the fifth-order experiment the signal is explicitly nonresonant and so only one phase component should exist, but as there exists the potential for several contributions to the signal, some desired and some not, each with potentially a different phase, it seems critically important to be able to heterodyne detect the signal. The DOE provides us with this feature free of charge and allows us to passively phase lock the reference field with a stability of λ/50. 4 Multicolor Approach In comparison with other fifth-order Raman experiments we are unique in that we use multiple colors for our pump and probe pulses.

The next modification to the FFMD simulation was to introduce a more accurate model for the many-body effects. The direct reaction field (DRF) model slightly modifies the DID model to also take into account electron wavefunction overlap effects. This more accurate model was initially used to calculate the third-order Raman response for liquid Xe and it proved to be slightly more accurate than the DID model in matching the experimental signal [51]. The real test of the model came when it was applied to both the third-order [52] and the fifth-order Raman response of CS2 [53].

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